煤颗粒在溶剂中的溶胀特性与动力学研究

    Study of the swelling characteristics and kinetics of coal particle in solvent

    • 摘要: 为了研究油煤浆预热过程中煤颗粒的溶胀特性与动力学,以无水乙醇、循环溶剂、四氢萘作为溶剂,采用位移传感器溶胀测量装置,研究煤样在不同溶剂中的溶胀特性与动力学。研究结果表明:煤样在乙醇中的溶胀试验重现性较好,装置较稳定;煤样在循环溶剂、四氢萘中的溶胀比随温度升高而增加,当温度升至315 ℃时膨胀比达到最大;基于试验建立的溶胀动力学模型,可以扩展应用于拟合煤样在循环溶剂和四氢萘中程序升温过程的溶胀数据,其拟合决定系数较高,拟合效果较好。

       

      Abstract: In order to investigate the swelling characteristics and the kinetics involved of coal particle during the oil slurry preheating process, a study is made of the swelling characteristics and kinetics of coal samples in different solvents using absolute ethanol, cyclic solvent and tetraline as solvents, and displacement sensor as swelling measurement device. Test result indicates that the coal sample in ethanol exhibits a rather stable swelling property and a reproducible result as evidenced by inactivity of the displacement sensor; whereas, in cyclic solvent and tetraline, the swelling ratio of the coal sample is seen to increase with the rise of temperature and reaches a maximum value at a temperature of 315 ℃. The swelling kinetics model developed based on the test result can be expanded for fitting the swelling data of coal samples in cyclic solvents and tetraline during the programmed heating process. Test shows a good fitting result with a high coefficient of determination can be obtained.

       

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