新型煤尘抑制剂制备技术与工艺研究

    Study of the new-type coal dust suppressant preparation technology and its preparation process

    • 摘要: 为了治理煤炭在生产和运输环节中产生的大量煤尘,选用具有丰富孔结构的海泡石作骨架材料,采用乳液聚合法将玉米秸秆和丙烯酸接枝共聚制备煤尘抑制剂,并进行了工艺条件优化和产品性能表征。试验结果表明:海泡石与玉米秸秆的比值为1.5,引发剂用量为10~15 mL,交联剂用量为1~2 g,丙烯酸用量为90~100 mL,聚合反应温度在45 ℃时是最佳工艺条件;当糊化温度在90 ℃、时间为30 min,聚合反应温度为45 ℃、时间为2 h时,制得的煤尘抑制剂具有较强的吸水能力;煤尘抑制剂经稀释后直接喷洒在煤堆表面,能够形成较为平整以及坚固的薄膜,当丙烯酸的含量越多,其成膜时间越短,成膜质地越牢固;抑制剂的耐蒸发性也十分可观,可在较长时间内保水。从煤尘抑制剂的相关物化性能表征以及性能测试可以看出,该煤尘抑制剂是一种高效的化学煤尘抑尘材料,直接反复喷淋在煤堆表面,能够取得较好的抑尘效果,防尘效果持续时间超过7 d,且不会对环境造成二次污染。该研究结果在煤尘治理方面具有良好的应用前景。

       

      Abstract: In order to control the large amount of coal dust generated during coal washing and transportation processes, a new-type dust suppressant is developed with porous structured sepiolite as skeletal material and grafted and copolymerized corn straw with acrylic acid, using emulsion polymerization method. The process conditions are optimized, and the effect of the suppressor is characterized. Test results indicate an optimal process conditions can be achieved at a sepiolite-corn straw ratio of 1.5, a dosage of initiator of 10~15 mL, a dosage of cross linking agent between 1 g and 2 g, a dosage of acrylic acid of 90~100 mL, and a polymerization temperature of 45 °C; when the gelatinization temperature maintains at 90 °C for 30 minutes with the polymerization temperature keeping at 45 °C for 2 hours, the prepared dust suppressant exhibits a high water absorption capacity; when the diluted, dust suppressant is directly sprayed onto the surface of a coal pile, a relatively flat and firm film can be formed; the higher the content of acrylic acid, the shorter the film forming time and the firmer the texture of the formed film; the suppressant demonstrates remarkably high evaporation-resistant and long-term water retaining capacities demonstrated by results of tests on physiochemical property and effects of the suppressant, the suppressant proves to be an efficient chemical coal dust suppression material. When directly and repeatedly sprayed onto the surface of the coal pile, a satisfactory dust suppression effect can be obtained with an effective time of more than 7 days without causing secondary environmental pollution. The research results have a broad application prospects for coal dust control.

       

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